It has been a major challenge to develop stable and cost-effective porous materials that efficiently recover heavy rare earth elements (HREEs) due to ever-increasing demand, low availability and high cost of HREEs. This study presents two novel benzylphosphate-based covalent porous organic polymers (BPOP-1 and BPOP-2) that were prepared by facile one-pot Friedel-Crafts reactions. Various analytical techniques are used to investigate the successful syntheses of BPOP materials and establish their material properties, which include an unusual crystalline nature, large surface area, hierarchical pore structure, and superior chemical stabilities. The BPOPs effectively adsorb, and thus remove HREEs from aqueous media. In particular, BPOP-1 had higher phosphate content and exhibits superior adsorption capacities (Eu³⁺: 289.5; Gd³⁺: 292.7; Tb³⁺: 294.4; Dy³⁺: 301.9 mg/g) than BPOP-2, while BPOP-2 had higher mesoporosity and correspondingly supports faster adsorption kinetics. Remarkably, both BPOP materials exhibit some of the highest HREE adsorption capacities reported to date, the selective capture of Dy³⁺ ions, and excellent cyclic adsorption/desorption properties. We provide a potential adsorption mechanism for Dy³⁺ capture by the BPOP adsorbent. These demonstrate that introducing phosphate functionality into a robust porous polymer backbone with high surface area is a promising strategy for selective HREEs capture from wastewater.

paper information

Journal of Hazardous Materials Volume 424, Part A, 15 February 2022, 127356

Received 12 May 2021, Revised 16 September 2021, Accepted 24 September 2021, Available online 26 September 2021, Version of Record 1 October 2021.

Authors: Seenu Ravi, Seo-Yul Kim, Youn-Sang Bae

DOI : https://doi.org/10.1016/j.jhazmat.2021.127356